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Related Experiment Videos

Sodium alpha-glucoheptonate dihydrate.

Y J Park1, B H Lee

  • 1Department of Chemistry, Sook Myung Women's University, Seoul, Korea 140-742. yjpark@sookmyung.ac.kr

Acta Crystallographica. Section C, Crystal Structure Communications
|February 15, 2001
PubMed
Summary

The crystal structure of sodium D-glycero-D-gulo-heptonate dihydrate reveals a bent carbon chain in the glucoheptonate anion. Extensive hydrogen bonding and distorted octahedral coordination of sodium ions were observed.

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Area of Science:

  • Carbohydrate Chemistry
  • Crystallography
  • Structural Chemistry

Background:

  • Sodium D-glycero-D-gulo-heptonate is a derivative of heptonic acid.
  • Understanding the solid-state structure of carbohydrate salts is crucial for various applications.

Purpose of the Study:

  • To determine the detailed crystal structure of sodium D-glycero-D-gulo-heptonate dihydrate.
  • To analyze the intermolecular interactions and coordination environment within the crystal lattice.

Main Methods:

  • Single-crystal X-ray diffraction was employed to elucidate the molecular and crystal structure.
  • Analysis of bond distances, angles, and hydrogen bonding networks was performed.

Main Results:

  • The glucoheptonate anion adopts a bent carbon chain conformation.

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  • Extensive intermolecular hydrogen bonds were identified involving hydroxyl and water molecules.
  • The sodium cation exhibits a distorted octahedral coordination with six oxygen atoms.
  • Conclusions:

    • The crystal structure provides insights into the solid-state behavior of sodium D-glycero-D-gulo-heptonate.
    • The observed hydrogen bonding and coordination geometry influence the compound's stability and properties.