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Two iridanonaborane compounds.

J Bould¹, J D Kennedy, M Thornton-Pett

¹School of Chemistry, The University of Leeds, Leeds LS2 9JT, England. bould@chem.leeds.ac.uk

Acta Crystallographica. Section C, Crystal Structure Communications

|February 15, 2001

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This study describes two novel iridanonaborane compounds. One compound, [Ir(B8H10Cl)(C3H9P)2(CO)], demonstrates significant chlorine-substituent migration during its synthesis.

Area of Science:

Organometallic Chemistry
Boron Chemistry
Coordination Chemistry

Background:

Iridanaboranes are a class of organometallic compounds featuring iridium and boron clusters.
Understanding their synthesis and reactivity is crucial for developing new materials and catalysts.

Purpose of the Study:

To synthesize and characterize two novel iridanonaborane compounds.
To investigate the chemical behavior and structural properties of these complexes.

Main Methods:

Synthesis of iridanonaborane complexes using specific precursors and reaction conditions.
Characterization of the synthesized compounds using spectroscopic and analytical techniques.

Main Results:

Successful synthesis of two iridanonaborane compounds: [IrH(B8H12)(C3H9P)2(CO)] (Ia) and [Ir(B8H10Cl)(C3H9P)2(CO)] (II).

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Compound (II) exhibited evidence of chlorine-substituent migration during its formation, indicating unique reactivity.

Conclusions:

The study successfully synthesized and characterized new iridanonaborane derivatives.
The observed chlorine migration in compound (II) highlights novel reaction pathways in iridanonaborane chemistry.