Related Experiment Video
Updated: Aug 12, 2026

High Pressure Single Crystal Diffraction at PX^2
Published on: January 16, 2017
Generalized extinction in bipyramidal crystals
Thorkildsen G1, Larsen HB, Semmingsen D
1Department of Mathematics and Natural Science, Stavanger University College, Ullandhaug, N-4091 Stavanger, Norway. gunnar.thorkildsen@tn.his.no
Abstract:
The generalized extinction factors for a set of strong reflections as a function of wavelength are obtained by indirect measurements. The experiments are performed on a crystalline system that satisfies the geometrical requirements imposed by theoretical models developed for a finite perfect crystal. With increased perfection, represented by a reduction in the width of the mosaic distribution function from three to one thousandth of a degree, the experiments give results that approach the predictions from the theory. The present procedure utilizes measurements of the integrated diffracted power of a weak reflection for scaling the strong reflections, hence non-measurable wavelength-dependent factors are assumed to be eliminated.
Related Concept Videos
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
The Seven Crystal Systems: Overview
Crystallographic Point Groups
Law of Rational Indices
Imperfections in Crystal Structure: Point, Line and Plane Defects

