Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Coordination polymers of copper(I) halides.

P M Graham1, R D Pike, M Sabat

  • 1Department of Chemistry, College of William and Mary, Williamsburg, Virginia 23187, USA.

Inorganic Chemistry
|March 10, 2001
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Acral Melanoma in the Caucasian Population: A Comprehensive Cohort Study on Epidemiological, Clinicopathological, and Prognostic Features.

Actas dermo-sifiliograficas·2025
Same author

Acral Melanoma in the Caucasian Population: A Comprehensive Cohort Study on Epidemiological, Clinicopathological, and Prognostic Features.

Actas dermo-sifiliograficas·2025
Same author

Corrigendum to <"Determination of microplastics in sediment, water, and fish across the Orange-Senqu River basin" [Water Research Volume 266 (2024) Number 122394].

Water research·2024
Same author

Determination of microplastics in sediment, water, and fish across the Orange-Senqu River basin.

Water research·2024
Same author

The discovery of (1R, 3R)-1-(3-chloro-5-fluorophenyl)-3-(hydroxymethyl)-1,2,3,4-tetrahydroisoquinoline-6-carbonitrile, a potent and selective agonist of human transient receptor potential cation channel subfamily m member 5 (TRPM5) and evaluation of as a potential gastrointestinal prokinetic agent.

Bioorganic & medicinal chemistry·2022
Same author

LightBox: A multiwell plate illumination system for photoactive molecule characterization.

Journal of biophotonics·2021
Same journal

Thermally Induced In-Lattice Cation Transformation of 0D Antimony Halides for Improved X-ray Scintillation.

Inorganic chemistry·2026
Same journal

Low-Valent Rhodium and Iridium Assemblies Directed by Uracilate and Guaninate Linkers.

Inorganic chemistry·2026
Same journal

Solid-State Syntheses, Crystallographic Spatial Disorders, Thermal Behavior, and Bandgaps of Hybrid Organic-Inorganic Manganese Halides: A<sub>2</sub>Mn(Cl/Br)<sub>4</sub> (A = NH<sub>4</sub>, C(NH<sub>2</sub>)<sub>3</sub>, & C<sub>3</sub>H<sub>4</sub>N<sub>2</sub>).

Inorganic chemistry·2026
Same journal

Comparing the Photophysical Properties of Bridged and Unbridged Platinum(II) Cyclometalated Complexes.

Inorganic chemistry·2026
Same journal

Solvent Coordination-Induced Synergistic Phase, Facet, and Defect Engineering of CdS for Photocatalytic Hydrogen Evolution.

Inorganic chemistry·2026
Same journal

Tailoring the Electron-Enriched Microenvironment of UiO-66 via Thiol Functionalization to Boost Non-Thermal Plasma CO<sub>2</sub> Conversion.

Inorganic chemistry·2026
See all related articles

This study synthesized 21 copper halide complexes with bridging ligands, revealing two main stoichiometries and structural types. Thermal decomposition and X-ray crystallography elucidated their structural diversity and stability trends.

Area of Science:

  • Coordination Chemistry
  • Materials Science
  • Crystallography

Background:

  • Copper halide complexes with bridging ligands are crucial in materials science.
  • Understanding their synthesis, stoichiometry, and structural characteristics is essential for developing new materials.

Purpose of the Study:

  • To synthesize and characterize novel copper halide complexes with various bridging ligands.
  • To investigate the influence of bridging ligands and copper halide stoichiometry on complex formation.
  • To determine the structural features and thermal stability of the synthesized complexes.

Main Methods:

  • Synthesis of 21 copper halide (CuX) complexes with bridging ligands (B).
  • Thermogravimetric analysis (TGA) to study thermal decomposition patterns.

Related Experiment Videos

  • X-ray crystallography to elucidate the solid-state structures of selected complexes.

    • Main Results:

    • Two main stoichiometries, [CuXB] (type 1) and [(CuX)2B] (type 2), were observed.
    • Structural diversity was confirmed by X-ray crystallography, revealing 2D sheets, 2D layers, and 1D chains.
    • A general decomposition trend (1 --> 2 --> [(CuX)2B(1/2)] --> CuX) was established.

    Conclusions:

    • The synthesis yielded a variety of copper halide complexes with tunable structures based on bridging ligands.
    • Stoichiometry and structural motifs are influenced by the choice of copper halide and bridging ligand.
    • The study provides insights into the structure-property relationships of these coordination compounds.