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Updated: Jul 29, 2026

Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
Published on: May 15, 2017
Two-dimensional dynamic-director (13)C NMR of liquid crystals
D McElheny1, M Zhou, L Frydman
1Department of Chemistry (M/C 111), University of Illinois at Chicago, 845 W. Taylor Street, Chicago, Illinois 60607-7061, USA.
Abstract:
A novel nuclear magnetic resonance (NMR) experiment for facilitating the resolution and assignment of liquid crystalline (13)C NMR spectra is described. The method involves the motor-driven reorientation of the liquid crystalline director, in synchrony with the acquisition of a 2D chemical shift correlation spectrum. By monitoring in this fashion the (13)C NMR evolution of spins in the liquid crystal at two different director orientations with respect to the magnetic field, the method distinguishes anisotropic from isotropic displacements and can be utilized for assigning the resonances and estimating local degrees of order. Of various potential pairs of angles suitable for such a correlation, the (0 degrees, 90 degrees ) choice was found to be most convenient, as it avoids line broadening complications that may otherwise originate from heterogeneities of the oriented phase. The technique thus derived was employed in the analysis of a series of monomeric and polymeric liquid crystal systems.
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