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Related Experiment Videos

Polymeric bis[bis(2,2'-bipyridine)-nickel(II)] hexavanadate(V).

B Z Lin1, S X Liu

  • 1Institute of Material Physical Chemistry, Huaqiao University, Quanzhou 362011, People's Republic of China. bzlin@hqu.edu.cn

Acta Crystallographica. Section C, Crystal Structure Communications
|March 16, 2001
PubMed
Summary

The study details the crystal structure of a novel vanadium oxide compound featuring nickel(II) complexes. This research provides insights into layered inorganic materials and their coordination chemistry.

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Area of Science:

  • Inorganic Chemistry
  • Crystal Engineering
  • Materials Science

Background:

  • Layered vanadium oxides are known for their diverse structural motifs and potential applications.
  • Coordination complexes, such as bis(2,2'-bipyridine)nickel(II), can be incorporated into inorganic frameworks.
  • Understanding the intercalation of complex cations within oxide layers is crucial for designing new materials.

Purpose of the Study:

  • To determine and describe the crystal structure of mu-hexavanadato(V)-bis[bis(2,2'-bipyridine)nickel(II)].
  • To investigate the structural relationship between this compound and similar zinc-based materials.
  • To elucidate the coordination environment of nickel(II) within the vanadium oxide framework.

Main Methods:

  • Single-crystal X-ray diffraction was employed to analyze the compound's structure.

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  • The crystal structure was solved and refined to atomic resolution.
  • Structural comparisons were made with isomorphous known compounds.

    • Main Results:

    • The structure consists of vanadium oxide layers intercalated by bis(2,2'-bipyridine)nickel(II) cations.
    • The vanadium oxide layers are constructed from corner-sharing VO(4) tetrahedra, forming a ruffled sinusoidal structure.
    • Nickel(II) ions exhibit cis coordination to two oxygen atoms from the vanadium oxide layer, with specific Ni-O bond distances.

    Conclusions:

    • The compound [(Ni(C(10)H(8)N(2))(2))(2)(V(6)O(17))] possesses a unique layered structure.
    • The intercalation of complex cations like [Ni(bipy)(2)](2+) influences the overall framework stability and dimensionality.
    • This work contributes to the understanding of structure-property relationships in hybrid inorganic-organic materials.