Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Doxylaminium tetrachlorocuprate(II).

K Braitenbach1, M Parvez

  • 1Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, Alberta, Canada T2N 1N4.

Acta Crystallographica. Section C, Crystal Structure Communications
|March 16, 2001
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Structure-property relationship of donor-acceptor acridones - an optical, electrochemical and computational study.

Physical chemistry chemical physics : PCCP·2015
Same author

Evaluation of the diagnostic value of immunocytochemistry and in situ hybridization in the pediatric leprosy.

Indian journal of leprosy·2014
Same author

Synthesis and characterization of the first stable cyanocyclophosphazenes.

Journal of the American Chemical Society·2011
Same author

Chelation of molybdenum in Medicago sativa (alfalfa) grown on reclaimed mine tailings.

Journal of agricultural and food chemistry·2008
Same author

Caulerpin.

Acta crystallographica. Section C, Crystal structure communications·2004
Same author

Synthetic and structural investigations of monomeric dilithium boraamidinates and bidentate NBNCN ligands with bulky N-bonded groups.

Inorganic chemistry·2004
Same journal

Intermolecular C-H···O, Cl···Cl and π-π interactions in the 2-dichloromethyl derivative of vitamin K3.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Isolation, pharmacological activity and structure determination of physalin B and 5β,6β-epoxyphysalin B isolated from Congolese Physalis angulata L.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Transannular S···N interactions in 10-ethynyl-10H-phenothiazine 5-oxide and 5,5-dioxide.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Two polymorphs of 2-ethyl-3-hydroxy-6-methylpyridinium hydrogen N-acetyl-L-glutamate from powder diffraction data.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Three-dimensional hydrogen-bonded assembly in 2,2'-disulfanylidene-5,5'-biimidazolidinylidene-4,4'-dione-dimethylformamide-water (3/2/4).

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Head-to-tail square-shaped cyclic hydrogen bonds leading to dimeric aggregates: 1,8-dibenzoyl-2,7-dihydroxynaphthalene and a comparison with its analogous benzoylnaphthalene.

Acta crystallographica. Section C, Crystal structure communications·2013
See all related articles

This study details the crystal structure of a doxylamine salt with tetrachlorocuprate(II). It reveals specific hydrogen bonding interactions and the characteristic flattened tetrahedral geometry of the copper complex anion.

Area of Science:

  • Inorganic Chemistry
  • Crystallography
  • Structural Chemistry

Background:

  • Doxylamine is an antihistamine with known sedative properties.
  • Tetrachlorocuprate(II) complexes exhibit diverse structural and electronic properties.
  • Understanding supramolecular interactions is crucial for materials science.

Purpose of the Study:

  • To elucidate the crystal structure of 2-[1-(dimethylammonioethoxy)-1-phenylethyl]pyridinium tetrachlorocuprate(II).
  • To investigate hydrogen bonding patterns within the crystal lattice.
  • To characterize the geometry of the tetrachlorocuprate(II) anion.

Main Methods:

  • Single-crystal X-ray diffraction analysis was performed.
  • The crystal structure was solved and refined.

Related Experiment Videos

  • Interatomic distances and angles were measured and analyzed.

    • Main Results:

    • The structure features doxylamine dihydro cations hydrogen bonded to tetrachlorocuprate(II) anions.
    • Specific Cl...N hydrogen bond distances were determined (3.101(9) and 3.253(10) Å).
    • The ethereal oxygen atom participates in intramolecular hydrogen bonds (2.517(11) and 2.757(12) Å), and the [CuCl(4)](2-) anion shows a flattened tetrahedral geometry.

    Conclusions:

    • The crystal structure provides detailed insights into the hydrogen bonding network of the doxylamine tetrachlorocuprate(II) salt.
    • The observed hydrogen bonds and anion geometry are consistent with expectations for such systems.
    • This structural characterization contributes to the understanding of coordination complexes and organic salts.