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Enantiomeric disorder in racemic cis-dichlorobis(pentane-2,4-dionato)titanium(IV)
1School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, Scotland.
Abstract:
The title compound, [Ti(C(5)H(7)O(2))(2)Cl(2)], adopts the cis configuration. The racemic compound crystallizes in space group P1 and each molecular site has 0.50 occupancy by each of the two enantiomorphs. The enantiomeric disorder is correlated in two dimensions.