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trans-Bis(ethanolamine-N,O)bis(saccharinato-N)copper(II).

V T Yilmaz1, O Andac, Y Topcu

  • 1Department of Chemistry, Faculty of Arts and Science, Ondokuz Mayis University, 55139 Kurupelit Samsun, Turkey. vtyilmaz@samsun.omu.edu.tr

Acta Crystallographica. Section C, Crystal Structure Communications
|March 16, 2001
PubMed
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This study details the crystal structure of a copper(II) complex featuring ethanolamine (Hea) and saccharinate (sac) ligands. The complex exhibits a distorted octahedral geometry around the central copper ion.

Area of Science:

  • Coordination Chemistry
  • Inorganic Chemistry
  • Crystallography

Background:

  • Copper(II) complexes are vital in various chemical and biological processes.
  • Saccharinate and ethanolamine ligands offer unique coordination properties.
  • Understanding metal-ligand interactions is key to designing novel functional materials.

Purpose of the Study:

  • To synthesize and characterize a novel copper(II) complex.
  • To elucidate the coordination geometry and bonding in the complex.
  • To investigate the structural features imparted by saccharinate and ethanolamine ligands.

Main Methods:

  • Single crystal X-ray diffraction analysis was employed.
  • The crystal structure of the title complex, [Cu(C(7)H(4)NO(3)S)(2)(C(2)H(7)NO)(2)], was determined.

Related Experiment Videos

  • Coordination geometry and bond distances were analyzed.

    • Main Results:

    • The copper(II) center adopts a distorted octahedral coordination.
    • Two ethanolamine (Hea) and two saccharinate (sac) ligands are present in a trans configuration.
    • Specific bond distances (Cu--O, Cu--N(Hea), Cu--N(sac)) were precisely determined.

    Conclusions:

    • The study provides a detailed structural description of a unique copper(II) complex.
    • The trans configuration of ligands influences the coordination environment.
    • This structural insight contributes to the field of coordination chemistry and materials science.