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Pressure-temperature phase transition diagram for wheat starch.

J P Douzals1, J M Perrier-Cornet, J C Coquille

  • 1ENSBANA, 1 Esplanade Erasme, F-21000 Dijon, France, and ENESAD, Boulevard O. de Serres, 21800 Quétigny, France.

Journal of Agricultural and Food Chemistry
|March 23, 2001
PubMed
Summary

Wheat starch gelatinization under pressure and temperature showed thermodynamic similarities to protein unfolding. Optimized conditions yielded complete gelatinization with reduced hydration compared to thermal methods.

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Area of Science:

  • Food Science
  • Biophysics
  • Thermodynamics

Background:

  • Starch gelatinization is crucial for food processing.
  • Understanding its behavior under varying pressure and temperature is essential.
  • Previous studies have explored thermal gelatinization, but pressure effects are less understood.

Purpose of the Study:

  • To investigate the pressure-temperature (P-T) phase diagram of wheat starch gelatinization.
  • To analyze the thermodynamic contributions to starch gelatinization.
  • To correlate P-T conditions with starch hydration and propose a hydration model.

Main Methods:

  • Wheat starch suspensions (5% dry matter) treated at pressures (0.1–600 MPa) and temperatures (-20 to 96°C).
  • Gelatinization rate measured by microscopic loss of birefringence, calibrated with differential scanning calorimetry.

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  • Starch hydration evaluated using the starch swelling index.
  • Main Results:

    • Isogelatinization curves resembled protein unfolding P-T diagrams.
    • Thermodynamic analysis suggested endothermic, athermic, or exothermic gelatinization reactions.
    • Specific P-T conditions influenced hydration, with lower pressure/temperature yielding less hydration.

    Conclusions:

    • Wheat starch gelatinization exhibits complex thermodynamic behavior under pressure and temperature.
    • Pressure-temperature treatments offer control over starch hydration during gelatinization.
    • An energetic hydration model was proposed based on experimental findings.