Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Pentafluorosulfanylnitramide salts.

M E Sitzmann1, R Gilardi, R J Butcher

  • 1Naval Surface Warfare Center, Indian Head Division, Maryland 20640, USA.

Inorganic Chemistry
|March 29, 2001
PubMed
Summary

New pentafluorosulfanylnitramide salts were synthesized and characterized. Structural analysis revealed significant differences compared to dinitramide salts, particularly in N-N bond lengths and central nitrogen atom angles, offering insights into inorganic salt chemistry.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Observation of Λ[over ¯]p→K^{+}π^{+}π^{-}π^{0} and Λ[over ¯]p→K^{+}π^{+}π^{-}2π^{0}.

Physical review letters·2026
Same author

Modulating Cytotoxicity in HeLa Cells <i>via</i> Aromatic Ring Variation in Cu(I) Complexes.

ACS applied bio materials·2026
Same author

[Efficacy and safety of combined immunotherapy and targeted therapy as adjuvant treatment for hepatocellular carcinoma with microvascular invasion after surgery].

Zhonghua yi xue za zhi·2026
Same author

[Chinese dentists in the War to Resist US Aggression and Aid Korea].

Zhonghua kou qiang yi xue za zhi = Zhonghua kouqiang yixue zazhi = Chinese journal of stomatology·2026
Same author

[Research advances on the application of artificial intelligence technology in the diagnosis and treatment of sepsis patients].

Zhonghua shao shang yu chuang mian xiu fu za zhi·2025
Same author

[Research progress on high-quality development of dietary nutrition and chronic disease big data].

Zhonghua yu fang yi xue za zhi [Chinese journal of preventive medicine]·2025

Area of Science:

  • Inorganic Chemistry
  • Crystallography
  • Materials Science

Background:

  • Pentafluorosulfanylnitramide salts (Z+SF5NNO2-) represent a novel class of inorganic compounds.
  • Previous research has explored dinitramide salts (Z+N(NO2)2-), providing a basis for comparison.

Purpose of the Study:

  • To describe the synthesis and properties of pentafluorosulfanylnitramide salts.
  • To structurally characterize these new salts using single-crystal X-ray diffraction.
  • To compare their structural features with those of dinitramide salts.

Main Methods:

  • Synthesis of pentafluorosulfanylnitramide salts via nucleophilic displacement from carbamates and ion exchange.
  • Isolation and characterization of synthesized salts.
  • Single-crystal X-ray diffraction for detailed structural analysis.

Related Experiment Videos

Main Results:

  • Successful preparation of various pentafluorosulfanylnitramide salts, though some exhibited instability.
  • X-ray crystallography revealed distinct structural differences between SF5NNO2- and N(NO2)2- anions.
  • SF5NNO2- salts exhibit a shorter N-N distance (1.308(9) Å) and an N-N-S angle close to sp2 hybridization (120.0(5)°).
  • The SF5 moiety in SF5NNO2- salts displayed high structural consistency, unlike the variable conformations of N(NO2)2-.

Conclusions:

  • Pentafluorosulfanylnitramide salts are a new class of inorganic compounds with unique structural characteristics.
  • Significant structural variations exist between pentafluorosulfanylnitramide and dinitramide anions, impacting their properties.
  • The SF5 group's structural integrity is maintained across different environments in these salts.