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Phase-field modeling of microstructural pattern formation during directional solidification of peritectic alloys
1Physics Department and Center for Interdisciplinary Research on Complex Systems, Northeastern University, Boston, Massachusetts 02115, USA.
Summary
Peritectic alloy solidification shows two microstructures: unstable cellular-dendritic arrays and stable layered bands. A new phase-field model explains the transition from islands to bands, revealing constant acceleration during peritectic phase spreading.
Area of Science:
- Materials Science
- Solidification Science
- Computational Materials Science
Background:
- Peritectic alloys exhibit complex microstructures during directional solidification.
- Microstructure formation depends on the temperature gradient/growth rate ratio (G/v(p)).
- Morphological stability of solid phases dictates growth patterns, from cellular-dendritic to layered structures.
Purpose of the Study:
- To develop and utilize a phase-field model for peritectic solidification.
- To investigate the formation of layered and island microstructures.
- To understand the transition dynamics between different peritectic growth morphologies.
Main Methods:
- Development of a phase-field model incorporating nucleation.
- Numerical simulations of peritectic solidification under varying conditions.
- Analysis of microstructure evolution, phase spreading dynamics, and morphology transitions.
Main Results:
- The model successfully reproduces observed peritectic microstructures, including bands and islands.
- Simulations reveal a constant acceleration in the lateral spreading of the peritectic phase.
- The study elucidates the morphology transition from islands to bands as a function of nucleation and growth dynamics.
Conclusions:
- Phase-field modeling provides crucial insights into peritectic solidification mechanisms.
- Nucleation and growth interplay governs microstructure formation in stable regimes.
- The findings predict growth morphologies relevant for larger-scale solidification processes.