Related Experiment Video
Updated: Aug 29, 2026

Disentangling High Strength Copolymer Aramid Fibers to Enable the Determination of Their Mechanical Properties
Published on: September 1, 2018
Exactness of the annealed and the replica symmetric approximations for random heteropolymers
1HLRZ, Forschungszentrum Jülich, D-52425 Jülich, Germany.
Abstract:
We study a heteropolymer model with random contact interactions introduced some time ago as a simplified model for proteins. The model consists of self-avoiding walks on the simple cubic lattice, with contact interactions between nearest-neighbor pairs. For each pair, the interaction energy is an independent Gaussian variable with mean value B and variance Delta(2). For this model the annealed approximation is expected to become exact for low disorder, at sufficiently high dimension and in the thermodynamic limit. We show that corrections to the annealed approximation in the three-dimensional high-temperature phase are small, but do not vanish in the thermodynamic limit, and are in good agreement with our replica symmetric calculations. Such corrections derive from the fact that the overlap between two typical chains is nonzero. We explain why previous authors had come to the opposite conclusion, and discuss consequences for the thermodynamics of the model. Numerical results were obtained by simulating chains of length N
Related Concept Videos
Polymers: Molecular Weight Distribution
Polymer Classification: Crystallinity
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Polymer Classification: Stereospecificity
Molecular Weight of Step-Growth Polymers
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
Determination of Molar Masses of Polymers I
Determination of Molar Masses of Polymers II

