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Poly[[[1,2-mu)-benzene]silver(I)-mu-trifluoromethanesulfonate-O;O';O":O"]
1Anorganisch-chemisches Institut, Ruprecht-Karls-Universität, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany. bu9@ix.urz.uni-heidelberg.de
Abstract:
The title compound, [Ag(CF(3)O(3)S)(C(6)H(6))], has been synthesized and characterized by low-temperature single-crystal X-ray diffraction. The complex is polymeric, with a network of trifluoromethanesulfonate anions bridging the silver cations. The terminal planar benzene ligand is asymmetrically eta(2)-coordinated to the Ag.