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Updated: Oct 8, 2026

Synthesis and Purification of Iodoaziridines Involving Quantitative Selection of the Optimal Stationary Phase for Chromatography
Published on: May 16, 2014
Sequential-injection procedure for determination of iodide in pharmaceutical and drinking water samples by catalytic
J A Erustes1, R Forteza, V Cerdà
1University of the Balearic Islands, Departament de Química, Palma de Mallorca, Spain.
Abstract:
A novel sequential-injection system was developed for determination of iodide at very low concentrations by using a kinetic method. The method is based on the catalytic effect of iodide on the redox reaction between Ce4+ and As3+ first described by Sandell and Kolthoff. The calibration curve is constructed by measuring the decrease of Ce4+ absorbance versus iodide concentration with a delay time of 30 s. The detection limit is 1.5 microg/L, the working temperature is 45 degrees C, and the working range is 0.002-0.5 mg/L. Reasonable agreement was obtained when the method was applied to pharmaceutical and drinking water samples. The method has a sample throughput of approximately 15/h.
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