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Published on: June 2, 2017
Current-induced embrittlement of atomic wires
T N Todorov1, J Hoekstra, A P Sutton
1School of Mathematics and Physics, The Queen's University of Belfast, Belfast BT7 1NN, United Kingdom. T.Todorov@qub.ac.uk
Electrical current causes gold atomic chains to become brittle and break more easily. This "embrittlement" limits the maximum current these atomic wires can safely conduct.
Area of Science:
- Condensed matter physics
- Materials science
- Nanotechnology
Background:
- Experiments show gold atomic contacts and chains fracture at 1-2 V.
- Understanding current's effect on defect-free atomic conductors is crucial.
Purpose of the Study:
- Investigate current-induced forces on gold atomic chains.
- Determine the mechanism behind current-induced fracture in atomic wires.
Main Methods:
- Calculated forces on atoms in a gold chain between gold electrodes.
- Analyzed the influence of current on the work required to break the chain.
Main Results:
- Current-induced forces alone are insufficient to break the gold chain.
- Current significantly lowers the energy barrier for chain fracture.
- Increased probability of thermally activated spontaneous fracture observed.
Conclusions:
- Current-induced embrittlement is the primary cause of fracture in gold atomic wires.
- This phenomenon establishes a fundamental limit on the current-carrying capacity of atomic-scale conductors.
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