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High-Resolution Infrared Spectrum of CD(3)CN: Analysis of the Interacting nu(3) and nu(6) Bands and Evaluation of the
S. Alanko1, M. Koivusaari, R. Paso
1Department of Physical Sciences, University of Oulu, Oulu, FIN-90014, Finland
Abstract:
The infrared spectrum in the range 900-1230 cm(-1) including the fundamental bands nu(3) and nu(6) of CD(3)CN has been studied. The resolution attained was 0.0025 cm(-1) in the measurement on the Bruker 120 HR Fourier spectrometer in Oulu. About 4000 lines were assigned in the nu(6) band. For the weak nu(3) band, which has not been observed earlier directly, we were able to assign 206 lines in three subbands K=8-10. These lines become detectable due to the strong nu(3)/nu(6) Coriolis resonance. There is also an l(1,-2) resonance between nu(3) and nu(6), which made it possible to obtain a value 2.647721(50) cm(-1) for the axial rotational constant A(0), when D(0)(K) from force field calculations was applied. Different types of resonances with the overtone 3nu(8) and the combinations nu(4)+nu(8) and nu(7)+nu(8) were observed. A fit with a standard deviation of 0.0019 cm(-1) was attained by using a model of 10 different resonances. Copyright 2001 Academic Press.
