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Updated: May 2, 2026

Simulation of the Planetary Interior Differentiation Processes in the Laboratory
Published on: November 16, 2013
The Earth's 'missing' niobium may be in the core
Niobium and vanadium behave similarly during Earth's core formation. This suggests niobium entered the core with vanadium, negating the need for deep-mantle niobium reservoirs.
Area of Science:
- Geochemistry
- Planetary Science
- Earth Science
Background:
- Earth's core formation involved segregation of metallic and silicate phases.
- Moderately siderophile elements like vanadium are depleted in the silicate mantle, suggesting core entry.
- Refractory lithophile elements (e.g., calcium, rare-earth elements) are not depleted, indicating they remained in the silicate portion.
Purpose of the Study:
- To investigate the partitioning behavior of niobium (Nb) between liquid metal and liquid silicate.
- To determine if Nb's depletion in the crust and upper mantle requires deep-mantle reservoirs.
- To compare Nb partitioning with that of vanadium (V), a known core-entering element.
Main Methods:
- High-pressure experiments simulating core-mantle differentiation.
- Analysis of element partitioning between metallic and silicate melts.
- Comparison of niobium and vanadium partitioning coefficients.
Main Results:
- Niobium and vanadium exhibit virtually identical partitioning behavior between liquid metal and liquid silicate at high pressure.
- The partitioning of Nb is consistent with that of V, a moderately siderophile element.
- Observed depletions of Nb in the crust and upper mantle can be explained by core partitioning, not hidden reservoirs.
Conclusions:
- Niobium likely entered Earth's core along with vanadium during planetary formation.
- The concept of deep-mantle niobium-rich reservoirs is unnecessary to explain observed depletions.
- This finding refines our understanding of Earth's early chemical differentiation and element distribution.
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