Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Nitroguanyl azide.

A D Vasiliev1, A M Astachov, A A Nefedov

  • 1Institute of Physics, Krasnoyarsk State University, Krasnoyarsk 660036, Russia. adva@ksc.krasn.ru

Acta Crystallographica. Section C, Crystal Structure Communications
|May 16, 2001
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Thermal, mechanical and biodegradation studies of biofiller based poly-3-hydroxybutyrate biocomposites.

International journal of biological macromolecules·2019
Same author

Correction: Synthesis and crystal structure of a new hexagonal perovskite 7H-Ba7Li1.75Mn3.5O15.75 with Mn(4+)/Mn(5+) charge distribution.

Dalton transactions (Cambridge, England : 2003)·2015
Same author

Synthesis and crystal structure of a new hexagonal perovskite 7H-Ba7Li1.75Mn3.5O15.75 with Mn(4+)/Mn(5+) charge distribution.

Dalton transactions (Cambridge, England : 2003)·2015
Same author

[Inheritance and phenotype expression of functional and null alleles of aromatic alcohol dehydrogenase (CAD) in diploid wheats].

Genetika·2015
Same author

[A syringe shower].

Khirurgiia·2010
Same author

Powder diffraction crystal structure analysis using derivative difference minimization: example of the potassium salt of 1-(tetrazol-5-yl)-2-nitroguanidine.

Acta crystallographica. Section B, Structural science·2005
Same journal

Intermolecular C-H···O, Cl···Cl and π-π interactions in the 2-dichloromethyl derivative of vitamin K3.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Isolation, pharmacological activity and structure determination of physalin B and 5β,6β-epoxyphysalin B isolated from Congolese Physalis angulata L.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Transannular S···N interactions in 10-ethynyl-10H-phenothiazine 5-oxide and 5,5-dioxide.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Two polymorphs of 2-ethyl-3-hydroxy-6-methylpyridinium hydrogen N-acetyl-L-glutamate from powder diffraction data.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Three-dimensional hydrogen-bonded assembly in 2,2'-disulfanylidene-5,5'-biimidazolidinylidene-4,4'-dione-dimethylformamide-water (3/2/4).

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Head-to-tail square-shaped cyclic hydrogen bonds leading to dimeric aggregates: 1,8-dibenzoyl-2,7-dihydroxynaphthalene and a comparison with its analogous benzoylnaphthalene.

Acta crystallographica. Section C, Crystal structure communications·2013
See all related articles

Nitrocarbamimidoyl azide, a compound with the chemical formula CH(2)N(6)O(2), crystallizes with two independent molecules. Its structure is stabilized by hydrogen bonds, revealing a unique nitrimine arrangement.

Area of Science:

  • Crystallography
  • Chemical structure analysis
  • Molecular interactions

Background:

  • The study focuses on the crystalline structure of nitrocarbamimidoyl azide (CH(2)N(6)O(2)).
  • Understanding molecular arrangements is crucial for predicting chemical properties and reactivity.
  • Hydrogen bonding plays a significant role in stabilizing crystal structures.

Purpose of the Study:

  • To determine the crystal structure of nitrocarbamimidoyl azide.
  • To analyze the intra- and intermolecular interactions within the crystal lattice.
  • To characterize the molecular geometry, specifically the presence of a nitrimine group.

Main Methods:

  • Single-crystal X-ray diffraction was employed to elucidate the crystal structure.
  • Crystallographic data was analyzed to identify symmetry elements and molecular arrangements.

Related Experiment Videos

  • Hydrogen bond networks were investigated through structural analysis.

    • Main Results:

    • The crystal structure of nitrocarbamimidoyl azide (CH(2)N(6)O(2)) was successfully determined.
    • Two symmetry-independent molecules were found within the unit cell.
    • The crystal structure is stabilized by a network of intra- and intermolecular hydrogen bonds.
    • The molecule was confirmed to possess a nitrimine structural motif.

    Conclusions:

    • The crystallographic analysis provides a detailed understanding of nitrocarbamimidoyl azide's solid-state structure.
    • The identified hydrogen bonding significantly contributes to the stability of the crystal.
    • The presence of the nitrimine structure is a key feature of this molecule.