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Updated: Oct 7, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
[Characterization of Ru(bpy)(3)2+ and Ru(phen)(3)2+ complexes with silver(i) ion of ground state in
1Veszprémi Egyetem, Altalános és Szervetlen Kémia Tanszék, H-8200 Veszprém, Egyetem u. 10.
Abstract:
Phosphorescent bimolecular and termolecular exciplexes of 3Ru(bpy)(3)2+ and Ru(phen)(3)2+ (bpy = 2,2'-bipyridine, and phen = 1,10-phenathroline) formed by silver ions of ground state in propylene carbonate solution are identified and characterized. Formation constants, lifetime, radiative and non-radiative decay constats of exciplexes are determined. Temperature-dependent luminescence lifetime measurements have revealed that exciplex formation causes a decrease in the energy level of the luminescent excited state.
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