Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Chromous hydrazine sulfate.

A W Parkins1, P D Prince, R A Smith

  • 1Department of Chemistry, King's College London, Strand, London WC2R 2LS, England. adrian.parkins@kcl.ac.uk

Acta Crystallographica. Section C, Crystal Structure Communications
|June 16, 2001
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Fluorescent carbon quantum dot hydrogels for direct determination of silver ions.

Talanta·2016
Same author

Lipopolysaccharide (LPS) induction of nitric oxide synthase-2 and cyclooxygenase-2 is impaired in fructose overloaded rats.

Life sciences·2010
Same author

Synthesis and characterization of gallium silylamido complexes.

Inorganic chemistry·2001
Same author

A novel recyclable sulfur monoxide transfer reagent.

Organic letters·2001
Same author

Oxonium ions from aqua regia: isolation by hydrogen bonding to crown ethers.

Inorganic chemistry·2001
Same author

Synthesis and structural characterization of tin(II) and zinc(II) derivatives of cyclic alpha-hydroxyketones, including the structures of Sn(maltol)(2), Sn(tropolone)(2), Zn(tropolone)(2), and Zn(hinokitiol)(2).

Inorganic chemistry·2001
Same journal

Intermolecular C-H···O, Cl···Cl and π-π interactions in the 2-dichloromethyl derivative of vitamin K3.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Isolation, pharmacological activity and structure determination of physalin B and 5β,6β-epoxyphysalin B isolated from Congolese Physalis angulata L.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Transannular S···N interactions in 10-ethynyl-10H-phenothiazine 5-oxide and 5,5-dioxide.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Two polymorphs of 2-ethyl-3-hydroxy-6-methylpyridinium hydrogen N-acetyl-L-glutamate from powder diffraction data.

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Three-dimensional hydrogen-bonded assembly in 2,2'-disulfanylidene-5,5'-biimidazolidinylidene-4,4'-dione-dimethylformamide-water (3/2/4).

Acta crystallographica. Section C, Crystal structure communications·2013
Same journal

Head-to-tail square-shaped cyclic hydrogen bonds leading to dimeric aggregates: 1,8-dibenzoyl-2,7-dihydroxynaphthalene and a comparison with its analogous benzoylnaphthalene.

Acta crystallographica. Section C, Crystal structure communications·2013
See all related articles

This study details the structure of a novel chromium(II) compound, [Cr(N2H5)2(SO4)2]. Researchers identified its unique chain structure and hydrogen bonding interactions at 100 K.

Area of Science:

  • Inorganic Chemistry
  • Crystallography
  • Materials Science

Background:

  • Understanding the structural properties of transition metal compounds is crucial for developing new materials.
  • Chromium(II) complexes exhibit diverse coordination environments and magnetic properties.

Purpose of the Study:

  • To elucidate the crystal structure of catena-poly[dihydraziniochromium(II)-di-mu-sulfato-O:O'], [Cr(N2H5)2(SO4)2].
  • To investigate the bonding and intermolecular interactions within the compound.

Main Methods:

  • Single-crystal X-ray diffraction at 100 K.
  • Experimental determination of hydrogen atom positions.

Main Results:

  • The compound features infinite chains of chromium(II) ions bridged by sulfate anions.

Related Experiment Videos

  • Hydrazinium ions are coordinated to the chromium centers.
  • The chromium atom is located on an inversion center.
  • All five hydrogen atoms of the hydrazinium ions participate in hydrogen bonding with sulfate oxygen atoms.

    • Conclusions:

    • The study provides a detailed structural characterization of the novel chromium(II) sulfate complex.
    • The identified hydrogen bonding network plays a significant role in stabilizing the crystal structure.