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Bis(O,O'-di-p-tolyldithiophosphato-S,S')(1,10-phenanthroline-N,N')nickel(II)
Q Hao1, H K Fun, S Chantrapromma
1Materials Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094, People's Republic of China.
Abstract:
The title coordination complex, [Ni(C14H14O2PS2)2(C12H8N2)] or [Ni(pMePh-dtp)2(phen)] (phen is 1,10-phenanthroline; dtp is diaryldithiophosphate), has a non-crystallographic twofold axis of symmetry through the Ni atom and the phen moiety. Two O,O-di-p-tolyldithiophosphate (dtp) ions act as bidentate ligands. The central metal atom is coordinated by four S atoms from two dtp groups and two N atoms from the phen ligand. The title compound displays distorted octahedral geometry around the central Ni atom.