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Related Experiment Videos

N-(4-Biphenylyl)urea.

S George1, A Nangia, V M Lynch

  • 1School of Chemistry, University of Hyderabad, Hyderabad 500 046, India.

Acta Crystallographica. Section C, Crystal Structure Communications
|June 16, 2001
PubMed
Summary
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The crystal structure of C13H12N2O reveals specific hydrogen bonding patterns. These include the formation of a urea alpha-network and an unusual N-H...pi interaction.

Area of Science:

  • Crystallography
  • Supramolecular Chemistry
  • Organic Chemistry

Background:

  • Hydrogen bonds are crucial in determining crystal structures and material properties.
  • Urea derivatives are known for their ability to form extensive hydrogen-bonding networks.

Purpose of the Study:

  • To elucidate the detailed crystal structure of the title compound, C13H12N2O.
  • To identify and characterize the hydrogen bonding interactions present in the crystal lattice.

Main Methods:

  • Single-crystal X-ray diffraction analysis was performed to determine the three-dimensional structure.
  • Analysis of intermolecular interactions, specifically hydrogen bonds, was conducted.

Main Results:

  • The crystal structure is characterized by N-H(anti)...O hydrogen bonds, forming a well-defined urea alpha-network.

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  • An unconventional N-H(syn)...pi hydrogen bond involving the N-H donor and a pi system was identified.
  • Conclusions:

    • The identified hydrogen bonding network, including the urea alpha-network and the N-H...pi interaction, dictates the packing and stability of the crystal structure.
    • This study contributes to the understanding of hydrogen bonding in organic compounds and provides insights into crystal engineering.