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Optimization and empirical modeling of HG-ICP-AES analytical technique through artificial neural networks
J F Magallanes1, P Smichowski, J Marrero
1Unidad de Actividad Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. del Libertador 8250, 1429 Buenos Aires, Argentina. magallan@cnea.gov.ar
Abstract:
An artificial neural network technique has been applied to the optimization of a hydride generation-inductively coupled plasma-atomic emission spectrometry (HG-ICP-AES) coupling for the determination of Ge at trace levels. The back propagation of errors net architecture was used. Experimental parameters and their relationship have been studied, obtaining a surface response of the system. The results and optimization aspects achieved with the neural network approach have been compared to the "one variable at time" and SIMPLEX methods.