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Synthesis of the cyclohexan subunit of baconipyrones A and B from furan
O Arjona1, R Menchaca, J Plumet
1Departamento de Química Orgánica I, Facultad de Química, Universidad Complutense, 28040 Madrid, Spain. arjonao@eucmax.sim.ucm.es
Organic Letters
|June 30, 2001
Abstract:
[figure: see text] The synthesis of the cyclohexan subunit of the siphonarlid metabolites baconipyrones A and B from furan is described. A key step included the alkylative ring opening of 7-oxanorbornenic sulfone 4 and oxidative desulfonylation of compound 8.