Related Experiment Videos
Catalytic ethenylation reaction of phenol using SnCl4
1Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, Aoba, Sendai 980-8578, Japan.
Organic Letters
|June 30, 2001
Abstract:
[figure: see text] Ethenylation reaction of phenol with silylethyne at the o-position is catalyzed by the SnCl4-BuLi reagent. While turn over numbers (TONs) in the reactions of m- or p-substituted phenols are 3 to 4, those for o-substituted phenols are 8 to 9.