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Thiadiazole-derived expanded heteroazaporphyrinoids
M K Islyaikin1, E A Danilova, L D Yagodarova
1Departamento de Química Orgánica (C-I), Universidad Autónoma de Madrid, Spain.
Organic Letters
|July 7, 2001
Abstract:
[structure: see text] Heteroannulenes 1 and 3 containing three subunits of isoindole or pyrrole, respectively, three 1,3,4-thiadiazole moieties, and six aza-bridges have been synthesized by reaction of the corresponding diiminoisoindoline or diiminopyrroline with 2,5-diamino-1,3,4-thiadiazole. These conjugated nonaromatic 30 pi-electron macrocycles coordinate three metal ions within their central cavity and constitute one of the rare examples of expanded heteroazaporphyrinoids.