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5-(2-pyridyl)-1,3-dithiane-2-thione
A Hazell1, C J McKenzie, J Nielsen
1Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Arhus C, Denmark. ach@chem.au.dk
Abstract:
The title compound, C9H9NS3, crystallizes with two molecules in the asymmetric unit. In both molecules, the dithiane-2-thione rings adopt a symmetric half-boat conformation with the C atom opposite the C--S(thione) bond out of the plane. The pyridine ring is in an equatorial position and is twisted out of the plane of the half-boat by 82.7 (2) and 84.5 (2) degrees in the two molecules, so that the N atom is trans to the axial C--H bond in both cases.