Time domain analysis: an alternative way to interpret PGSE experiment

We report a theoretical development which aims at interpreting Pulsed Gradient Spin Echo data for diffusing fluids in saturated porous media. It consists in analyzing the time dependence of PGSE amplitudes for each single gradient strength, and introduces a new diffusion coefficient D(q) as being continuously dependent on the length scale in the material. Both experimental measurements on water saturated bead packings and simulated experiments in 2D and 3D model systems are interpreted with this approach. D(q) is shown to give a new insight in the micro-macro transition. Its evolution vs. the length scale is non trivial, and can be sensitive to local slow kinetic effects.