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Molecular-orbital study of hydroxylation of collagenous proline and lysine
R Zahradník1, P Hobza, J Hurych
1Institute of Physical Chemistry, Czechoslovak Academy of Sciences, Prague, Czechoslovakia.
Biochimica Et Biophysica Acta
|December 28, 1971
Abstract:
EHT and CNDO/2 types of calculations permit the interpretation of the course of hydroxylation of collagenous proline and lysine. Calculations were performed for the models of proline (I), zwitterion of proline (II), proline-containing peptide (III), and lysine (IV). The theoretical results are consistent with an electrophilic mechanism.