Surface ordering above the isotropic-smectic-A transition at a silane-treated substrate

Surface ordering in a homologous series of alkyl cyanobiphenyl (nCB) liquid crystals having a direct isotropic-smectic-A (I-A) transition was investigated using evanescent-wave ellipsometry. The liquid crystal was bounded by a solid substrate treated with a silane surfactant which induced homeotropic (perpendicular) ordering of the liquid crystal molecules in the smectic-A phase. In the isotropic phase, one of the liquid crystals (10CB) partially wet the interface with an orientationally ordered, homeotropically aligned layer. The ordered interfacial layer grew without layering transitions but remained finite in thickness as the bulk I-A transition was approached. The interfacial layer has significantly lower orientational order than is observed in the smectic phase, indicating the possibility that the surface region of 10CB may be in a surface-induced, nonspontaneous nematic phase. The other liquid crystals (11 and 12CB) showed no surface ordering behavior whatsoever. Models describing the ordered surface layer of 10CB are presented. The results can be interpreted as a sharp transition in the surface ordering behavior as the chain length of the liquid crystal is varied, at the I-A transition of a liquid crystal.