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Ribbon phase in a phase-separated lyotropic lamellar-sponge mixture under shear flow
G Cristobal1, J Rouch, P Panizza
1Centre de Physique Moléculaire Optique et Hertzienne, Université Bordeaux I, 351 Cours de la Libération, 33400 Talence, France.
Abstract:
We report the effect of shear flow on a phase-separated system composed of lyotropic lamellar (L(alpha)) and sponge (L3) phases in a mixture of brine, surfactant, and cosurfactant. Optical microscopy, small-angle light, and x-ray scattering measurements are consistent with the existence of a steady state made of multilamellar ribbon-like structures aligned in the flow direction. At high shear rates, these ribbon-like structures become unstable and break up into monodisperse droplets resulting in a shear-thickening transition.