Search research articles

ABOUT JoVE

Overview Leadership Blog JoVE Help Center

AUTHORS

Publishing Process Editorial Board Scope & Policies Peer Review FAQ Submit

LIBRARIANS

Testimonials Subscriptions Access Resources Library Advisory Board FAQ

RESEARCH

JoVE Journal Methods Collections JoVE Encyclopedia of Experiments Archive

EDUCATION

JoVE Core JoVE Business JoVE Science Education JoVE Lab Manual Faculty Resource Center Faculty Site

Terms & Conditions of Use

Search research articles

Related Experiment Videos

Platinum(II) hydrazido complexes.

A Xia¹, P R Sharp

¹Department of Chemistry, University of Missouri, 125 Chemistry, Columbia, MO 65211, USA.

Inorganic Chemistry

|July 24, 2001

Summary

This study details the synthesis of novel platinum-hydrazine complexes, including bridging 1,2-dimethylhydrazido and phenylhydrazido ligands. These reactions showcase new platinum coordination chemistry with substituted hydrazines.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by

Same author

[Microbiota structure and diversity in <i>Aedes albopictus</i> at different developmental stages].

Zhongguo xue xi chong bing fang zhi za zhi = Chinese journal of schistosomiasis control·2022

Same author

[Cyclic thrombocytopenia: a case report and literature review].

Zhonghua xue ye xue za zhi = Zhonghua xueyexue zazhi·2021

Same author

[Hereditary coagulation factor XIII deficiency: three cases report and literaure review].

Zhonghua xue ye xue za zhi = Zhonghua xueyexue zazhi·2021

Same author

Treatment with a neutrophil elastase inhibitor and ofloxacin reduces P. aeruginosa burden in a mouse model of chronic suppurative otitis media.

NPJ biofilms and microbiomes·2021

Same author

Transcriptomic analysis reveals the inhibition of reproduction in rice brown planthopper, Nilaparvata lugens, after silencing the gene of MagR (IscA1).

Insect molecular biology·2021

Same author

[A single-center clinical analysis of 65 cases of pseudomyxoma peritonei from appendiceal origin in the early stage].

Zhonghua zhong liu za zhi [Chinese journal of oncology]·2019

Area of Science:

Organometallic Chemistry
Coordination Chemistry
Platinum Complexes

Background:

Platinum complexes are crucial in catalysis and medicine.
Hydrazine derivatives offer diverse coordination possibilities.
Understanding platinum-hydrazine interactions is key for novel material design.

Purpose of the Study:

To synthesize and characterize novel platinum complexes with hydrazine ligands.
To explore the reactivity of platinum hydroxo complexes with substituted hydrazines.
To elucidate the structural features of the resulting platinum-hydrazido and platinum-hydroxo-hydrazido complexes.

Main Methods:

Reaction of platinum hydroxo complexes with 1,2-dimethylhydrazine and phenylhydrazine.
Isolation and purification of platinum-hydrazido products.
Single-crystal X-ray diffraction for structural determination of key complexes.

Main Results:

Synthesis of a bridging 1,2-dimethylhydrazido(-2) platinum complex, [(dppp)2Pt2(μ-η2:η2-MeNNMe)](BF4)2.
Formation of platinum complexes with bridging hydroxo and dimethylhydrazido ligands, [(dppp)2Pt2(μ-OH)(μ-NHNMe2)](OTf)2.
Characterization of platinum complexes with bridging hydroxo and phenylhydrazido ligands, [(dppp)2Pt2(μ-OH)(μ-NHNHPh)](OTf)2, and a bis(phenylhydrazido) complex, [(dppp)Pt(μ-NHNHPh)]2(X)2.

Conclusions:

The study successfully synthesized and structurally characterized new platinum complexes featuring diverse hydrazine-derived ligands.
The reactivity of platinum hydroxo complexes with substituted hydrazines leads to the formation of bridging hydrazido and hydroxo-hydrazido species.
These findings expand the scope of platinum coordination chemistry and offer insights into metal-ligand bonding with hydrazine derivatives.

Related Experiment Videos