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Sodium 2-nitroethanaloximate forms a layered-framework structure.

G Ferguson1, A J Lough, D M Smith

  • 1School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, Scotland.

Acta Crystallographica. Section C, Crystal Structure Communications
|August 11, 2001
PubMed
Summary
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This study details the crystal structure of a sodium compound, revealing a unique coordination network. The sodium ions and anions form extended chains through shared octahedra, stabilized by hydrogen bonds.

Area of Science:

  • Solid-state chemistry
  • Crystallography
  • Coordination chemistry

Background:

  • Understanding the structural properties of coordination compounds is crucial for developing new materials.
  • Sodium compounds exhibit diverse structural motifs and bonding characteristics.

Purpose of the Study:

  • To elucidate the crystal structure and bonding of the title compound, [Na(C(2)H(3)N(2)O(3))].
  • To investigate the coordination environment of sodium ions and the arrangement of anions.
  • To characterize the intermolecular interactions, including hydrogen bonding, within the crystal lattice.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the crystal structure.
  • Analysis of atomic positions, coordination numbers, and bond distances.

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  • Identification and analysis of hydrogen bonding networks (O-H...O and C-H...O).

    • Main Results:

    • The compound crystallizes in the P2(1)/m space group with the Na(+) cation at a center of inversion.
    • Sodium ions are octahedrally coordinated by four oxygen and two nitrogen atoms from six distinct anions.
    • A 3D network is formed by chains of confacial octahedra, linking anion layers through Na-anion coordination.
    • Anions are interconnected within layers via O-H...O and C-H...O hydrogen bonds.

    Conclusions:

    • The crystal structure reveals a unique coordination polymer formed by sodium ions and the specified anion.
    • The interplay of coordination bonds and hydrogen bonds dictates the overall supramolecular architecture.
    • This structural insight contributes to the understanding of crystal engineering in coordination compounds.