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Radermachera xylocarpa: the highly efficient source of lapachol and synthesis of its derivatives

N P Shetgiri1, S V Kokitkar, S N Sawant

  • 1Department of Chemistry, The Institute of Science, Mumbai, India.

Acta Poloniae Pharmaceutica
|August 15, 2001
PubMed

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Compounds bearing two hydroxyl groups are known as diols. When the hydroxyl groups are located on adjacent carbon atoms, the diols are called vicinal diols or glycols. Under acidic conditions, vicinal diols undergo a specific reaction called pinacol rearrangement.
The reaction begins with transferring a proton from the acid catalyst to one of the hydroxyl groups, producing an oxonium ion.