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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
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Mono- and dinuclear five-coordinate cyclometalated palladium(II) compounds.

M López-Torres1, A Fernández, J J Fernández

  • 1Departamento de Química Fundamental, Universidad de La Coruña, E-15071 La Coruña, Spain.

Inorganic Chemistry
|August 21, 2001
PubMed
Summary

New palladium(II) complexes with a triphosphine ligand were synthesized. These complexes feature five-coordinate palladium centers, with one complex being the first doubly cyclometalated palladium(II) compound with two pentacoordinated metal centers.

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