Characterisation of non-condensable sulphur containing gases from Kraft pulp mills

This paper describes work performed on the sampling and analysis of non-condensable gases (NCG) emitted from diffuse sources of a Portuguese Kraft pulp mill, which is the background information for a NCG collection, treatment and disposal system. The variability found in the composition of the gaseous compounds showed the existence of gaseous streams other than typical total reduced sulphur (TRS) compounds as usually described. From the measured TRS concentrations and the gas flow rate from each source it was possible to calculate the emission flow rate, E, of each source. These emission flow rates were then divided into three categories which are quite useful to identify significant sources and to choose abatement techniques. The methodology presented allows for a precise quantification of sources so that similar emissions can be grouped for treatment purposes. Sources with an emission flow rate bigger than 1 kg/h have a marked effect on the overall TRS emissions of the mill, as they are major contributors. It was also found that a new analytical procedure using Restek columns is more easy to use and overcomes operational problems noticed previously, namely a run time of 20-25 min instead of 50-60 min.