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Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR
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59Co chemical shift anisotropy and quadrupole coupling for K3Co(CN)6 from MQMAS and MAS NMR spectroscopy

U G Nielsen1, H J Jakobsen, J Skibsted

  • 1Instrument Centre for Solid-State NMR Spectroscopy, Department of Chemistry, University of Aarhus, Denmark.

Solid State Nuclear Magnetic Resonance
|September 1, 2001
PubMed

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Splitting diagrams or splitting tree diagrams are routinely used to depict such complex couplings. While drawing splitting diagrams, the splitting with the larger coupling constant is usually applied first.
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Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
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2D NMR: Homonuclear Correlation Spectroscopy (COSY)

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