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Using anion exchange resins to remove THM precursors.
1Boyle Engineering Corp., Bakersfield, CA 93302, USA.
Summary
Controlling trihalomethanes (THMs) involves understanding organic fractions. Ion exchange systems effectively target specific molecular weights to minimize THM formation potential in water treatment.
Area of Science:
- Environmental Science
- Water Chemistry
- Analytical Chemistry
Background:
- Trihalomethanes (THMs) are disinfection byproducts of concern in drinking water.
- Understanding the reactivity of different organic matter fractions is crucial for effective water treatment.
- Ion exchange and granular activated carbon (GAC) are common water treatment technologies.
Purpose of the Study:
- To investigate the control of trihalomethanes (THMs) using ion exchange.
- To compare the trihalomethane formation potentials of various organic fractions in influent water.
- To evaluate the effectiveness of different water treatment systems in reducing THM precursors.
Main Methods:
- Comparing THM formation potentials of organic fractions (<0.5K, 0.5K-1K, 1K-5K apparent molecular weight [AMW]).
- Analyzing influent water treated by three column systems: ion exchange, granular activated carbon (GAC), and combined ion exchange-GAC.
- Assessing the reactivity of organic fractions with free available chlorine.
Main Results:
- The smallest organic fraction (<0.5K AMW) exhibited the highest reactivity with free available chlorine.
- Ion exchange systems primarily produced THMs from 1K-5K, 0.5K-1K, and <0.5K AMW fractions.
- Combined ion exchange-GAC and GAC systems showed the <0.5K AMW fraction as the main THM producer.
Conclusions:
- Regeneration of ion exchange resin at sulfate breakthrough is effective.
- Combining ion exchange with GAC significantly reduces THM formation potential.
- Optimized ion exchange and GAC treatment can yield water with very low THM formation potential.