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Interstellar cyanomethane.

B E Turner1, P Friberg, W M Irvine

  • 1National Radio Astronomy Observatory, USA.

The Astrophysical Journal
|June 1, 1990
PubMed
Summary
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The abundance ratio of cyanomethane radical (CH2CN) to acetonitrile (CH3CN) varies with temperature in interstellar clouds. This ratio, decreasing with higher temperatures, suggests CH2CN forms via reactions involving nitrogen and hydrocarbons.

Area of Science:

  • Astrochemistry
  • Interstellar Medium Chemistry
  • Molecular Spectroscopy

Background:

  • Investigating the formation pathways of interstellar molecules is crucial for understanding chemical evolution in space.
  • Cyanomethane radical (CH2CN) and acetonitrile (CH3CN) are nitrogen-bearing molecules found in interstellar clouds.
  • Previous models have proposed specific chemical reactions and recombination processes for these species.

Purpose of the Study:

  • To study the abundance ratio of CH2CN to CH3CN in different interstellar environments.
  • To elucidate the role of CnHm(+) + N reactions in astrochemistry.
  • To test models of dissociative electron recombination, specifically Bates's models.

Main Methods:

  • Observational study of CH2CN and CH3CN in interstellar sources like TMC-1 and Sgr B2.
Keywords:
NASA Discipline ExobiologyNASA Discipline Number 52-10NASA Program ExobiologyNon-NASA Center

Related Experiment Videos

  • Analysis of abundance ratios in relation to environmental parameters, particularly temperature.
  • Comparison of observed ratios with theoretical predictions for chemical pathways.
  • Main Results:

    • A significantly different CH2CN/CH3CN abundance ratio was observed between TMC-1 and Sgr B2, attributed to temperature differences.
    • The CH2CN/CH3CN ratio shows a monotonic increase as temperature decreases from 10 K to 120 K.
    • Two new detections of CH2CN support the observed trends and temperature dependence.

    Conclusions:

    • The temperature dependence of the CH2CN/CH3CN ratio suggests CH2CN destruction via reaction with oxygen, or different formation pathways.
    • If oxygen destruction is significant, the molecules do not serve as a direct test for Bates's dissociative recombination models.
    • CH2CN likely forms via the C2H4(+) + N reaction, validating its importance in astrochemistry and explaining the observed temperature dependence.