Related Experiment Video
Updated: Jun 24, 2026

Reducing Willow Wood Fuel Emission by Low Temperature Microwave Assisted Hydrothermal Carbonization
Published on: May 19, 2019
Low-Mr hydrocarbons generated during hydrous and dry pyrolysis of kerogen
1Institute of Geophysics and Planetary Physics, University of California, Los Angeles 90024, USA.
Abstract:
The validity of applying laboratory pyrolysis experiments to simulating the maturation of organic matter in sedimentary basins has been vigorously debated. We report here results from the generation of hydrocarbons of low relative molecular mass (Mr) in both hydrous and dry pyrolysis. A principal difference is that under dry conditions in the presence of montmorillonite, catalysis occurs with respect to generation of low-Mr hydrocarbons but no such effect is evident for hydrous conditions, probably because of a reduction in the clay's acidity. In addition, olefins which were previously reported as not being present in the products of hydrous pyrolyses were found to be produced in the C2-C6 range in comparable amounts under both hydrous and dry pyrolyses at 300 degrees C and may form in the course of kerogen catagenesis in nature but disappear with geologic time due to their instability. These studies have relevance to understanding the interactions between kerogen and minerals in sedimentary rocks and to processes in the formation of natural gas.
Related Concept Videos
The Carbon Cycle
Limiting Reactant
Standard Enthalpy of Formation
Catalysis
Microbes and the Carbon Cycle
Microbes and Methanogenesis

