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Updated: Jul 17, 2026

Analysis of Volatile and Oxidation Sensitive Compounds Using a Cold Inlet System and Electron Impact Mass Spectrometry
Published on: September 5, 2014
Detection of interstellar ethylene oxide (c-C2H4O)
J E Dickens1, W M Irvine, M Ohishi
1Five College Radio Astronomy Observatory, University of Massachusetts, Amherst 01003, USA. dickens@fcrao1.phast.umass.edu
Astronomers detected cyclic ethylene oxide (c-C2H4O) in Sgr B2N, finding its abundance is over 200 times higher than predicted. This suggests that grain chemistry plays a significant role in its formation.
Area of Science:
- Astrochemistry
- Radio Astronomy
- Molecular Astrophysics
Background:
- The chemical composition of interstellar clouds is crucial for understanding star and planet formation.
- Cyclic molecules, such as ethylene oxide (c-C2H4O), are of particular interest due to their potential role in prebiotic chemistry.
- Previous models predicted low abundances of c-C2H4O in dense interstellar regions like Sagittarius B2.
Purpose of the Study:
- To detect and quantify the abundance of cyclic ethylene oxide (c-C2H4O) in the Sgr B2N star-forming region.
- To compare the observed abundance with predictions from current chemical models.
- To investigate the potential formation pathways of c-C2H4O in interstellar environments.
Main Methods:
- Observed molecular transitions of c-C2H4O in Sgr B2N using radio telescopes.
- Analyzed spectral data, performing Gaussian fits to detected lines.
- Utilized rotation diagram analysis to determine rotational temperature and column density.
Main Results:
- Successfully identified 10 transitions supporting the detection of c-C2H4O in Sgr B2N.
- Determined a rotational temperature of 18 K and a molecular column density of 3.3 x 10^14 cm^-2.
- Measured a fractional abundance of c-C2H4O relative to molecular hydrogen of approximately 6 x 10^-11, over 200 times higher than predicted.
Conclusions:
- The significantly higher-than-expected abundance of c-C2H4O suggests that current gas-phase chemical models are incomplete.
- Results strongly indicate that grain surface chemistry plays a crucial role in the formation of c-C2H4O in interstellar clouds.
- No detection of c-C2H4O in Sgr B2M or Sgr B2NW suggests localized formation or specific environmental conditions in Sgr B2N.
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