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Radical abdominal hysterectomy

N R Abu-Rustum1, W J Hoskins

  • 1Department of Surgery, Memorial Sloan-Kettering Cancer Center, New York, New York, USA.

The Surgical Clinics of North America
|September 12, 2001
PubMed

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Radical Formation: Elimination00:51

Radical Formation: Elimination

Another method of radical formation is the elimination process. It is the opposite of the addition route and is driven by the instability of the radical. For example, as depicted in Figure 1, dibenzoyl peroxide yields a pair of unstable radicals upon homolysis. Given its instability, this radical spontaneously undergoes elimination via a C–C bond cleavage to form a relatively more stable phenyl radical. The mechanism involves cleavage of the bond between the α and β positions with respect to...