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Enantioselective synthesis of ancepsenolide and its analogs
1Department of Bioscience and Biotechnology, Faculty of Agriculture, Shinshu University, Kamiina, Nagano, Japan.
Bioscience, Biotechnology, and Biochemistry
|October 2, 2001
Abstract:
Ancepsenolide (1a-s) and the enantiomer (1a-r) were respectively synthesized from (S)- and (R)-2-[(R)-O-MEM-mandeloyloxylpropanal (3a-s and 3a-r) and diisopropyl hexadecanedioate (5). The analogs (1b, 2a and 2b) were synthesized by a similar method.