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Nature of charge carriers in disordered molecular solids: are polarons compatible with observations?
P E Parris1, V M Kenkre, D H Dunlap
1Department of Physics, University of Missouri-Rolla, Rolla, MO 65409, USA.
Physical Review Letters
|October 3, 2001
Abstract:
Polaronic theories for charge transport in disordered organic solids, particularly molecularly doped polymers, have been plagued by issues of internal consistency related to the magnitude of physical parameters. We present a natural resolution of the problem by showing that, in the presence of correlated disorder, polaronic carriers with binding energies Delta approximately 50-500 meV and transfer integrals J approximately 1-20 meV are completely consistent with the magnitudes of field and temperature dependent mobilities observed.