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Total Synthesis of cis- and trans-3-Hydroxy-D-proline and (+)-Detoxinine
Johann Mulzer1, Andreas Meier, Jürgen Buschmann
1Institut für Kristallographie der Freien Universität Berlin, Takustrasse 6, D-14195 Berlin, Germany.
The Journal of Organic Chemistry
|January 26, 1996
Abstract:
The unnatural enantiomer of the amino acid detoxinine and both diastereomeric 3-hydroxy-D-prolines have been prepared from D-mannitol via the O-silylated hydroxyproline 12 as a common key intermediate.