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Variation in the Mode of Coordination of Aryl Sulfonates to Zirconocene in the Solid State

Nicola S. Hüsgen1, Gerrit A. Luinstra, Frank Schaper

  • 1Department of Chemistry, University of Konstanz, Fach M738, D-78457 Konstanz, Germany.

Inorganic Chemistry
|October 24, 2001
PubMed

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Structural Isomerism

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Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can be...
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Regioselectivity and Stereochemistry of Hydroboration

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Stereoisomerism02:52

Stereoisomerism

Isomerism in Complexes
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Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
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