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Trinuclear Lanthanoid Complexes of 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol with a Unique, Sandwich-Type Cage
Roman Hedinger1, Michele Ghisletta, Kaspar Hegetschweiler
1Laboratorium für Anorganische Chemie, ETH Zentrum, CH-8092 Zürich, Switzerland, Universität des Saarlandes, Fachrichtung Anorganische Chemie, Postfach 15 11 50, D-66041 Saarbrücken, Germany, Institut de Chimie Minérale et Analytique, Université de Lausanne-BCH, CH-1015 Lausanne, Switzerland, Dipartimento di Chimica, Università di Firenze, 50144 Florence, Italy, and Institut für Kristallographie, ETH Zentrum, CH-8092 Zürich, Switzerland.
Abstract:
A variety of trinuclear complexes [M(3)(H(-)(3)L)(2)](3+) [M = Y, La, Eu, Gd, Dy; L = 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (taci) and 1,3,5-trideoxy-1,3,5-tris(dimethylamino)-cis-inositol (tdci)] was prepared as solid materials of the composition M(3)(H(-)(3)L)(2)X(3).pH(2)O.qEtOH (X = Cl, NO(3); 2.5