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Potassium oxoantimonate(V), K(3)[SbO(4)].

C Hirschle¹, J Rosstauscher, C Röhr

¹Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstrasse 21, D-79104 Freiburg, Germany.

Acta Crystallographica. Section C, Crystal Structure Communications

|November 14, 2001

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Potassium oxoantimonate, K(3)[SbO(4)], crystallizes in a monoclinic structure. This study reveals chains of [SbO(6)] octahedra, offering insights into inorganic crystal structures.

Area of Science:

Inorganic Chemistry
Crystallography
Solid-State Chemistry

Background:

Oxoantimonates are inorganic compounds containing antimony-oxygen anions.
Understanding the crystal structures of these compounds is crucial for exploring their properties.

Purpose of the Study:

To determine the crystal structure of potassium oxoantimonate, K(3)[SbO(4)].
To characterize the coordination environment of antimony within the structure.

Main Methods:

Single-crystal X-ray diffraction was used to determine the crystal structure.
Analysis of atomic positions and coordination polyhedra.

Main Results:

K(3)[SbO(4)] crystallizes in the monoclinic space group P2/c, adopting the Na(3)[BiO(4)] structure type.

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The structure features chains of [SbO(6)] octahedra linked by common edges.

Potassium and antimony atoms are located on twofold rotation axes.

Conclusions:

The crystal structure of K(3)[SbO(4)] has been elucidated.
The arrangement of [SbO(6)] octahedra forms characteristic chains, providing a basis for understanding related oxoantimonate structures.