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Related Experiment Videos

Potassium oxoantimonate(V), K(3)[SbO(4)].

C Hirschle1, J Rosstauscher, C Röhr

  • 1Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstrasse 21, D-79104 Freiburg, Germany.

Acta Crystallographica. Section C, Crystal Structure Communications
|November 14, 2001
PubMed
Summary

Potassium oxoantimonate, K(3)[SbO(4)], crystallizes in a monoclinic structure. This study reveals chains of [SbO(6)] octahedra, offering insights into inorganic crystal structures.

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beta-Rubidium antimonide, Rb4Sb4.

Acta crystallographica. Section C, Crystal structure communications·2001

Area of Science:

  • Inorganic Chemistry
  • Crystallography
  • Solid-State Chemistry

Background:

  • Oxoantimonates are inorganic compounds containing antimony-oxygen anions.
  • Understanding the crystal structures of these compounds is crucial for exploring their properties.

Purpose of the Study:

  • To determine the crystal structure of potassium oxoantimonate, K(3)[SbO(4)].
  • To characterize the coordination environment of antimony within the structure.

Main Methods:

  • Single-crystal X-ray diffraction was used to determine the crystal structure.
  • Analysis of atomic positions and coordination polyhedra.

Main Results:

  • K(3)[SbO(4)] crystallizes in the monoclinic space group P2/c, adopting the Na(3)[BiO(4)] structure type.

Related Experiment Videos

  • The structure features chains of [SbO(6)] octahedra linked by common edges.
  • Potassium and antimony atoms are located on twofold rotation axes.

    • Conclusions:

    • The crystal structure of K(3)[SbO(4)] has been elucidated.
    • The arrangement of [SbO(6)] octahedra forms characteristic chains, providing a basis for understanding related oxoantimonate structures.